A Convenient Synthesis of Primary 2-Hydroxyorganophosphines from Red Phosphorus and Oxiranes

S. N. Arbuzova; L. Brandsma; N. K. Gusarova; A. H. T. M. van der Kerk; M. C. J. M. van Hooijdonk; B. A. Trofimov

doi:10.1055/s-2000-6238

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Synthesis 2000; 2000(1): 65-66
DOI: 10.1055/s-2000-6238

short paper

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A Convenient Synthesis of Primary 2-Hydroxyorganophosphines from Red Phosphorus and Oxiranes

S. N. Arbuzova^* , L. Brandsma, N. K. Gusarova, A. H. T. M. van der Kerk, M. C. J. M. van Hooijdonk, B. A. Trofimov

^*Irkutsk Institute of Chemistry of the Russian Academy of Sciences, Siberian Branch, Favorsky Street 1, 664033, Irkutsk, Russia; E-mail: arbuzova@irioch.irk.ru

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Publication Date:
31 December 2000 (online)

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A number of 2-hydroxyorganophosphines HOCH(R¹)CH(R²)PH₂ 2 have been obtained in good yields by reaction of oxiranes with sodium monophosphide, generated in situ from red phosphorus, sodium and tert-butyl alcohol in liquid ammonia.

phosphines - oxiranes - ring opening - phosphorus - sodium - liquid ammonia