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Synthesis 2000; 2000(6): 778-780
DOI: 10.1055/s-2000-6274
short paper
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Synthesis of Alkenylboronates via Palladium-Catalyzed Borylation of Alkenyl Triflates (or Iodides) with Pinacolborane

Miki Murata* , Takashi Oyama, Shinji Watanabe, Yuzuru Masuda
  • *Department of Materials Science, Kitami Institute of Technology, Kitami, 090-8507, Japan; Fax +81 (1 57) 26 49 73; E-mail: MASUDA-Yuzuru/mtrl@king.cc.kitami-it.ac.jp
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Publication Date:
31 December 2000 (online)

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Various alkenyl iodides and triflates were borylated with pinacolborane in the presence of Et3N and a catalytic amount of PdCl2(dppf) and AsPh3 to afford the corresponding alkenylboronates in good yields.

boron - hydrides - palladium - halides - cross-coupling - triflates