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Synthesis 2000; 2000(3): 407-410
DOI: 10.1055/s-2000-6349
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Superacidic Cyclization of All-trans-ω-Acetoxyfarnesyl Benzyl Ether

Veaceslav KulciŢki* , Nicon Ungur, Pavel F. Vlad, Margherita Gavagnin, Francesco Castelluccio, Guido Cimino
  • *Institutul de Chimie al Academiei de ŞiinŢe, str. Academiei 3, MD 2028 Chişinaˇu, Republic of Moldova; Fax + 37 32-73 97 75; E-mail: vlad@terp.ich.asm.md
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Publication Date:
31 December 2000 (online)

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The superacidic cyclization of all-trans-ω-acetoxyfarnesyl benzyl ether 2 begins at the internal double bond giving a mixture of diastereomeric monocyclic compounds 5 and 6, prenylated at gem-dimethyl groups

cyclizations - superacids - terpenoids - carbocations