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Synlett 2000; 2000(1): 83-85
DOI: 10.1055/s-2000-6438
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A Radical Versatile Synthesis of 2-Iodomethylene Cycloalkanols

Maud Chareyron* , Priscille Devin, Louis Fensterbank, Max Malacria
  • *Université P. et M. Curie, Laboratoire de Chimie Organique de Synthèse, associé au CNRS, Tour 44-54, B. 229, 4, place Jussieu, 75252 Paris Cedex, France; E-mail: malacria@ccr.jussieu.fr
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Publication Date:
31 December 2000 (online)

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A radical sequence involving a stannyl radical addition followed by cyclization onto a carbonyl group affords 2-iodo cyclopentanols and cyclohexanols.

radical reactions - tin - cyclizations - iodolysis - stereoselective synthesis