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Synlett 2001; 2001(2): 0281-0283
DOI: 10.1055/s-2001-10791
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Fluoride Ion-Assisted Cross-Coupling Reactions of (α-Fluorovinyl)diphenylmethylsilane with Aryl Iodides Catalyzed by Pd(0)/Cu(I) Systems

Takeshi Hanamoto* , Tomoko Kobayashi, Michio Kondo
  • *Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan; Fax (81)-952-28-8704; E-mail: hanamoto§cc.saga-u.ac.jp
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Publication Date:
31 December 2001 (online)

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The palladium-catalyzed cross-coupling reactions of (α-fluorovinyl)diphenylmethylsilane with organic halides in the presence of Cu(I) halide afford good yields of α-fluorovinyl organic compounds.

cross-coupling reaction - 2-fluorinated terminal olefin - (α-fluorovinyl)diphenylmethylsilane - palladium catalyst - cuprous iodide