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Synthesis 2003(1): 0053-0062
DOI: 10.1055/s-2003-36256
PAPER
© Georg Thieme Verlag Stuttgart · New York

Enantiomerically Pure cis- and trans-2-Substituted Cyclopropanols from Allylic Sulfones

David Díez*, Pilar García, Isidro S. Marcos, Narciso M. Garrido, Pilar Basabe, Julio G. Urones
Dpto. de Química Orgánica, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain
Fax: +34(923)294574; e-Mail: ddm@usal.es;
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Publication History

Received 24 July 2002
Publication Date:
18 December 2002 (online)

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Abstract

Enantiomerically pure cis- and trans-2-substituted cyclopropanols have been obtained from allylic sulfones derived from (R)-glyceraldehyde, in good yields.

Key words

cyclopropanols - sulfones - cyclization - synthesis

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