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Synthesis 2003(14): 2173-2178
DOI: 10.1055/s-2003-41078
DOI: 10.1055/s-2003-41078
PAPER
© Georg Thieme Verlag Stuttgart · New York
An Efficient Route to Aliphatic 2,2-Dichloroaldehydes via Chlorination of Aldehydes or Alcohols with the System Cl2/Quaternary Ammonium Chloride
Further Information
Received
30 April 2003
Publication Date:
24 September 2003 (online)
Publication History
Publication Date:
24 September 2003 (online)
Abstract
An effective and low waste method for preparing aliphatic 2,2-dichloroaldehydes has been achieved by halogenation of aldehydes or alcohols with Cl2, using tetraalkylammonium chlorides as recoverable catalysts.
Key words
alcohols - aldehydes - halogen - halogenation - halide
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