Synthesis 2006(10): 1635-1638  
DOI: 10.1055/s-2006-926440
PAPER
© Georg Thieme Verlag Stuttgart · New York

Simple Preparation of O-Substituted Hydroxylamines from Alcohols

Sébastien Albrecht, Albert Defoin*, Céline Tarnus
Laboratoire de Chimie Organique et Bioorganique, UMR 7015, École Nationale Supérieure de Chimie de Mulhouse, Université de Haute-Alsace, 3 rue Alfred Werner, 68093 Mulhouse Cédex, France
Fax: +33(3)89336875 ; e-Mail: A.Defoin@uha.fr;
Further Information

Publication History

Received 23 December 2005
Publication Date:
11 April 2006 (online)

Abstract

A direct preparation of O-substituted hydroxylamines from alcohols is described by O-alkylation of tert-butyl N-hydroxy­carbamate with the methanesulfonates of respective alcohols, followed by acidic N-deprotection.