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Banert, K. et al.: 2015 Science of Synthesis, 2014/4: Knowledge Updates 2014/4 DOI: 10.1055/sos-SD-101-00511
Knowledge Updates 2014/4

6.1.42 Product Subclass 42: N-Heterocyclic Carbene Borane Complexes

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Book

Editors: Banert, K.; Hall, D. G.; Joule, J. A.; Moloney, M. G.; Reissig, H.-U.; Schaumann, E.

Authors: Bredenkamp, A.; Heimgartner, H.; Kantlehner, W.; Kirsch, S. F.; Kwiecień, H.; Lacôte, E.; Mlostoń, G.; Vallet, A.-L.; Wyatt, P. B.

Title: Knowledge Updates 2014/4

Print ISBN: 9783131763211; Online ISBN: 9783131975614; Book DOI: 10.1055/b-003-125861

1st edition © 2015 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

N-Heterocyclic carbene borane complexes are a family of new reagents for organic chemistry and polymer synthesis. This chapter summarizes first the preparations and modifications of these reagents. It then focuses on the applications of the title compounds as radical hydrogen-atom donors, hydrides, hydroborating reagents, and radical photopolymerization initiators.

Key words

anionic reagents - boranes - borohydrides - boron compounds - carbenes - hydroboration - polymers - radical reactions - reductions
 
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