2.12.18 Chiral Scandium Complexes in Asymmetric Synthesis

W. Li; X. H. Liu; X. M. Feng

doi:10.1055/sos-SD-102-00633

Knowledge Updates 2021/1

DOI: 10.1055/b000000476

2.12.18 Chiral Scandium Complexes in Asymmetric Synthesis

Jiang, X.; Marek, I.; Marschner, C.; Montchamp, J.-L.; Reissig, H.-U.; Wang, M.;

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Abstract

Chiral scandium complexes have been widely used in asymmetric synthesis during the last two decades. In this chapter, representative achievements in scandium-catalyzed enantioselective reactions, published between 2003 and 2019, are highlighted. Reaction types covered include aldol-type reactions, Mannich-type reactions, Michael reactions, Friedel–Crafts reactions, rearrangements of carbonyl compounds with diazo compounds, ene-type reactions, photocatalytic reactions, ring-opening reactions, and cycloadditions.

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