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2.12. 18 Chiral Scandium Complexes in Asymmetric Synthesis
Book
Editors: Jiang, X.; Marek, I.; Marschner, C.; Montchamp, J.-L.; Reissig, H.-U.; Wang, M.
Title: Knowledge Updates 2021/1
Print ISBN: 9783132441958; Online ISBN: 9783132441972; Book DOI: 10.1055/b000000476
1st edition © 2021 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Knowledge Updates
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Type: Multivolume Edition
Abstract
Chiral scandium complexes have been widely used in asymmetric synthesis during the last two decades. In this chapter, representative achievements in scandium-catalyzed enantioselective reactions, published between 2003 and 2019, are highlighted. Reaction types covered include aldol-type reactions, Mannich-type reactions, Michael reactions, Friedel–Crafts reactions, rearrangements of carbonyl compounds with diazo compounds, ene-type reactions, photocatalytic reactions, ring-opening reactions, and cycloadditions.
Key words
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