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Jiang, X. et al.: 2021 Science of Synthesis, 2021/1: Knowledge Updates 2021/1 DOI: 10.1055/sos-SD-102-00633
Knowledge Updates 2021/1

2.12.18 Chiral Scandium Complexes in Asymmetric Synthesis

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Book

Editors: Jiang, X.; Marek, I.; Marschner, C.; Montchamp, J.-L.; Reissig, H.-U.; Wang, M.

Authors: Błażewska, K.; Feng, X. M.; Grimmer, J.; Gudat, D. ; Hlina, J. A. ; Justyna, K.; Kashemirov, B. A.; Krieg, S.-C.; Li, W.; Liu, X. H.; Lyu, J.; Manolikakes, G. ; McKenna, C. E.; Singh, F. V. 

Title: Knowledge Updates 2021/1

Print ISBN: 9783132441958; Online ISBN: 9783132441972; Book DOI: 10.1055/b000000476

1st edition © 2021 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 


Abstract

Chiral scandium complexes have been widely used in asymmetric synthesis during the last two decades. In this chapter, representative achievements in scandium-catalyzed enantioselective reactions, published between 2003 and 2019, are highlighted. Reaction types covered include aldol-type reactions, Mannich-type reactions, Michael reactions, Friedel–Crafts reactions, rearrangements of carbonyl compounds with diazo compounds, ene-type reactions, photocatalytic reactions, ring-opening reactions, and cycloadditions.

Key words

asymmetric catalysis - chiral compounds - scandium complexes - aldol reaction - Mannich reaction - Michael addition - Friedel–Crafts alkylation - diazo compounds - allylation - photochemistry - ring-opening reactions - cycloaddition
 
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