4.4.34.35 Vinylsilanes (Update 2015)

Abstract

This chapter is an update to the earlier Science of Synthesis contribution (Section 4.4.34) describing methods for the synthesis of vinylsilanes. It focuses on the literature published in the period 2000–2014, with a particular emphasis on metal-catalyzed methods.

Key words

vinylsilanes - vinylmetals - transition-metal catalysis - hydrosilylation - alkynes - silylmetalation - alkynylsilanes - hydrogenation - hydrometalation - coupling reactions - dehydrogenative silylation - alkenes - carbometalation - metathesis - rearrangements

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