4.4.6 Product Subclass 6: Silyltin Reagents

Abstract

This chapter describes the synthesis of silyltin reagents, also frequently called silylstannanes, and their synthetic applications via silicon-tin σ-bond activation. Transition-metal catalysts and non-transition-metal nucleophilic activators can be used for this purpose, leading to a wide range of silicon-installing and tin-installing reactions that provide direct and efficient access to synthetically useful organosilanes and organostannanes.

Key words

silyltin reagents - silylstannanes - silylation - stannylation - silicon compounds - tin compounds - palladium catalysts - copper catalysts - nickel catalysts - platinum catalysts - cyanides - chlorides - fluorides

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