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Donohoe, T. J. et al.: 2022 Science of Synthesis, 2022/3: Knowledge Updates 2022/3 DOI: 10.1055/sos-SD-104-00776
Knowledge Updates 2022/3

4.4.6 Product Subclass 6: Silyltin Reagents

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Book

Editors: Donohoe, T. J.; Huang, Z. ; Marschner, C. ; Oestreich, M. 

Authors: Jackowski, O. ; Marschner, C. ; Ohmiya, H. ; Perez-Luna, A. ; Pinto, D. C. G. A. ; Rocha, D. H. A. ; Santos, C. M. M. ; Silva, V. L. M. ; Sumida, Y. ; Takeda, N. ; Tang, X.; Yoshida, H. 

Title: Knowledge Updates 2022/3

Print ISBN: 9783132452848; Online ISBN: 9783132452862; Book DOI: 10.1055/b000000643

1st edition © 2022 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 


H. Yoshida 

Abstract

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This chapter describes the synthesis of silyltin reagents, also frequently called silylstannanes, and their synthetic applications via silicon-tin σ-bond activation. Transition-metal catalysts and non-transition-metal nucleophilic activators can be used for this purpose, leading to a wide range of silicon-installing and tin-installing reactions that provide direct and efficient access to synthetically useful organosilanes and organostannanes.

Key words

silyltin reagents - silylstannanes - silylation - stannylation - silicon compounds - tin compounds - palladium catalysts - copper catalysts - nickel catalysts - platinum catalysts - cyanides - chlorides - fluorides
 
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