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Fernández, E. et al.: 2021 Science of Synthesis, 2021/2: Knowledge Updates 2021/2 DOI: 10.1055/sos-SD-105-00314
Knowledge Updates 2021/2

5.1.7 Product Subclass 7: Germylenes

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Book

Editors: Fernández, E.; Huang, Z.; Jiang, X.; Koch, G.; Marschner, C.; Wang, M.

Authors: Chand, K. ; Davies, G. H. M.; Dorairaj, D. P.; Guo, R.; Hsu, S. C. N. ; Isovitsch, R.; Jiang, X.; Růžička, A.; Sirvinskas, M.; Takeda, N.; Trofimova, A.; Umesh; Vrána, J.; Wang, M.; Wisniewski, S. R.; Xiong, Y.; Ye, Z.-S.; Yudin, A. K.; Zhang, G. Z. 

Title: Knowledge Updates 2021/2

Print ISBN: 9783132442061; Online ISBN: 9783132442085; Book DOI: 10.1055/b000000477

1st edition © 2021 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

This chapter is a revised and updated version of the previous Science of Synthesis contribution describing methods for the synthesis of germylenes. As starting materials for the synthesis of germylenes, dihalogermanes and stable germanium(II) compounds {for example, GeCl2•dioxane, GeI2, and Ge[N(SiMe3)2]2} have been used since the 1970s. In recent decades, digermynes and some new stable germanium(II) compounds such as chlorogermylenes, aminogermylenes, borylgermylenes, and hydrogermylene dimers have been synthesized, and these species have also been used as starting materials for the synthesis of germylenes.

Key words

germylenes - digermynes - germynes - digermanes - dihalogermanes - substitution - reduction - dissociation - insertion - addition
 
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