9.9.6 Furans (Update 2024)

Abstract

This review is an update to the earlier Science of Synthesis contributions presenting methods for the synthesis of furans. It focuses on the literature published between 2011 and 2022. In the last decade, a number of new methods for the synthesis of furans from acyclic functionalized molecules have been developed. Many of the methods are based on (mixed) transition-metal catalysis, which induces several combinations of isomerizations, rearrangements, and cyclizations, leading to reactions that are termed cycloisomerizations. Multicomponent reactions for the synthesis of furans are also included.

Key words

furans - transition metals - ring closure - oxidative cyclization - ring contraction - ring expansion - ring transformation - tandem reactions - isomerization - catalysis

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