15.3.5 Synthesis of Quinoline Derivatives by Modification of a Methyl Substituent at the C2 or C8 Position

U. Sharma; D. Parmar; null Sumit; null Manisha

doi:10.1055/sos-SD-115-01542

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Campagne, J.-M. et al.: 2024 Science of Synthesis, 2024/2: Knowledge Updates 2024/2 DOI: 10.1055/sos-SD-115-01542

Knowledge Updates 2024/2

15.3.5 Synthesis of Quinoline Derivatives by Modification of a Methyl Substituent at the C2 or C8 Position

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Editors: Campagne, J.-M. ; Donohoe, T. J.; Jiang, X. ; Wang, M.

Authors: Cellnik, T. ; de Figueiredo, R. M. ; Deng, G.-J. ; Dong, K. ; Healy, A. ; Huang, H. ; Ji, X. ; Jo, W. ; Manisha ; Murai, T. ; Parmar, D. ; Sawamura, M. ; Sharma, U. ; Shimizu, Y. ; Sumit ; Yang, Z.

Title: Knowledge Updates 2024/2

Online ISBN: 9783132457065; Book DOI: 10.1055/b000000968

1st edition © 2024 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates

Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

This review is an update contribution covering methodologies reported between the years 2005–2022 for the side-chain modification of quinolines. The focus is on the literature published for the transformation of a “methyl group” at the C2 and C8 position of quinoline. Various metal-catalyzed and metal-free protocols for C(sp³)—H functionalization are described.

Key words

quinolines - methylquinolines - 8-methylquinoline - metal-free C(sp3)—H functionalization - metal-catalyzed C(sp3)—H functionalization - C(sp3)—C/C(sp3)—X bond formation - C—H functionalization - C—H activation

1 We are thankful to the Director of CSIR-IHBT, for providing the necessary facilities and to CSIR (under ANB theme MLP0159). Ms. Diksha and Ms. Manisha acknowledge UGC, New Delhi, for SRF fellowships. Mr. Sumit thanks DST for the INSPIRE-SRF fellowship. CSIR-IHBT communication no. for this manuscript is 5300.

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