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Campagne, J.-M.  et al.: 2024 Science of Synthesis, 2024/1: Knowledge Updates 2024/1 DOI: 10.1055/sos-SD-122-00021
Knowledge Updates 2024/1

22.1.7.2 Thioamides (Update 2024)

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Book

Editors: Campagne, J.-M. ; Donohoe, T. J.; Fürstner, A. ; Jiang, X. ; Wang, M. 

Authors: Cheng, J. ; Chowdhury, S. ; Harris, P. A. ; Li, X. ; Liu, M. ; Liao, L.; Song, Q. ; Tang, R.-Y. ; Tobrman, T. ; Wang, L.; Wu, X.-F. ; Ying, J. ; Yu, J.-S. ; Zhang, Y.

Title: Knowledge Updates 2024/1

Online ISBN: 9783132457058; Book DOI: 10.1055/b000000967

1st edition © 2024 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Laboratory Techniques, Stoichiometry;Organometallic Chemistry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 


Abstract

This is an update to the earlier Science of Synthesis contribution describing methods for the synthesis of thioamides, with a focus on the literature published in the period 2005–2022. In this time, a number of new synthetic methods for the preparation of thioamides have been developed. A variety of substrates, including amides, aldehydes, ketones, nitriles, carboxylic acids, thiocarboxylic acids, β-oxo carboxylic acids, alkynes, alkenes, oximes, benzylamines, benzylic alcohols, benzylic thiols, benzyl disulfides, active methylene compounds, and isothiocyanates, have been applied in these transformations. The sulfur agents used include Lawesson’s reagent, elemental sulfur, sulfide salts, phosphorus pentasulfide, thiourea, dithiophosphate, carbon disulfide, and thiophosphoryl chloride.

Key words

thioamides - amides - aldehydes - ketones - nitriles - carboxylic acids - alkynes - alkenes - oximes - active methylene compounds - isothiocyanates - sulfur
 
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