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Fernández, E. et al.: 2021 Science of Synthesis, 2021/2: Knowledge Updates 2021/2 DOI: 10.1055/sos-SD-127-00466
Knowledge Updates 2021/2

27.28 Product Class 28: β-Diketimines (1,3-Diimines)

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Editors: Fernández, E.; Huang, Z.; Jiang, X.; Koch, G.; Marschner, C.; Wang, M.

Authors: Chand, K. ; Davies, G. H. M.; Dorairaj, D. P.; Guo, R.; Hsu, S. C. N. ; Isovitsch, R.; Jiang, X.; Růžička, A.; Sirvinskas, M.; Takeda, N.; Trofimova, A.; Umesh; Vrána, J.; Wang, M.; Wisniewski, S. R.; Xiong, Y.; Ye, Z.-S.; Yudin, A. K.; Zhang, G. Z. 

Title: Knowledge Updates 2021/2

Print ISBN: 9783132442061; Online ISBN: 9783132442085; Book DOI: 10.1055/b000000477

1st edition © 2021 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

β-Diketimines, encountered frequently as “nacnac” ligands, have emerged as popular motifs among other ancillary supports. There has been a great deal of interest in these compounds as supporting ligands because of their strong binding to metal ions, their tunable steric and electronic effects, and their diversity in terms of bonding modes. A classical synthetic approach towards β-diketimines is direct condensation of pentane-2,4-diones (and 1,3-diketone analogues) with suitable amines in the presence of an acid source. Recent developments involve the use of molecular sieves to avoid purification problems and to improve yields. Herein, a thorough survey of the synthetic approaches to β-diketimine ligands and their metal complexes, and applications in coordination chemistry, has been compiled.

Key words

β-diketimines - 1,3-diimines - nacnac ligands - β-diketiminate ligands - condensation reactions - 1,3-diketones - amines - coordination chemistry
 
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