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Bagley, M. et al.: 2018 Science of Synthesis: Knowledge Updates 2018/3 DOI: 10.1055/sos-SD-130-00265
Knowledge Updates 2018/3

30.4.3 S,N-Acetals (α-Amino Sulfur Derivatives) (Update 2018)

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Book

Editors: Bagley, M.; Banert, K.; Joule, J. A.; Murai, T.; Ramsden, C. A.

Authors: Aitken, R. A.; Glushkov, V.; González-Bello, C.; Kwiecien, H.; Mutoh, Y.; Nakata, M.; Saikawa, Y.; Shklyaev, Y.

Title: Knowledge Updates 2018/3

Print ISBN: 9783132423213; Online ISBN: 9783132423244; Book DOI: 10.1055/b-006-161208

1st edition © 2018 Thieme. All rights reserved.
Georg Thieme Verlag, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Faul, M.; Fürstner, A. (Editor-in-Chief); Kobayashi, S.; Koch, G.; Molander, G.; Nevado, C.; Trost, B. M.; You, S.

Type: Multivolume Edition

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Abstract

This chapter is an update to the earlier Science of Synthesis contribution (Section 30.4) describing methods for the synthesis of S,N-acetals (also known as N,S-acetals or α-amino sulfur derivatives) that have been reported since 2003. One of the major recent developments involves the enantioselective synthesis of S,N-acetals by organocatalysis.

Key words

S,N-acetals - α-amino sulfur derivatives - alkynylation - nucleophilic addition - phase-transfer catalysis - asymmetric catalysis - acid catalysts - electrophilic additions - cycloadditions - sulfur compounds - thiols - iminium salts
 
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