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Brøndsted Nielsen, M. et al.: 2018 Science of Synthesis, 2018/1: Knowledge Updates 2018/1 DOI: 10.1055/sos-SD-132-00139
Knowledge Updates 2018/1

32.2.6 Monofunctionalized Allenes (Update 2018)

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Book

Editors: Brøndsted Nielsen, M.; Krause, N.; Rademann, J.; Ramsden, C. A.; Reissig, H.-U.

Authors: Ayad, T.; Bajić, M.; Blanc, A.; González-Bello, C.; Hashmi, A. S. K.; Hessel, V.; Kingston, M.; Pale, P.; Pirat, J.-L.; Pittelkow, M.; Ulfkjaer, A.; Virieux, D.; Volle, J.-N.; Weibel, J.-M.; Žnidaršič-Plazl, P.

Title: Knowledge Updates 2018/1

Print ISBN: 9783132423138; Online ISBN: 9783132423169; Book DOI: 10.1055/b-005-145253

1st edition © 2018 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Koch, G.; Molander, G. A.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

This chapter is an update to Science of Synthesis Section 32.2, covering the synthesis of allenes bearing one heteroatom substituent on the cumulated diene core. It covers the literature from 2008 to 2016. Many routes to these allenes start from alkynes, enynes, or propargylic systems and the syntheses proceed through substitution/rearrangement, but reactions involving the modification of an existing allene core are also included. In recent years, the synthesis of enantiomerically pure allenes has been of particular interest.

Key words

allenes - haloallenes - allenyl ethers - allenyl sulfides - allenylamides - allenylamines - allenylphosphorus compounds - allenylsilanes - rearrangement - isomerization - alkynes - enynes - propargylic systems
 
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