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Brøndsted Nielsen, M. et al.: 2014 Science of Synthesis, 2014/2: Knowledge Updates 2014/2 DOI: 10.1055/sos-SD-135-00029
Knowledge Updates 2014/2

35.2.1.3.5 Synthesis by Substitution of Carbon Functionalities (Update 2014)

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Book

Editors: Brøndsted Nielsen, M.; Krause, N.; Marek, I.; Schaumann, E.; Wirth, T.

Authors: Aguilar, E.; Beier, P.; Fuchibe, K.; Ghorai, S.; Heimgartner, H.; Ibis, C.; Ichikawa, J.; Lipshutz, B. H.; Liu, Q.; López, L. A.; Margaretha, P.; Mlostoń, G.; Shneider, O. S.; Szpilman, A. M.; Vilhelmsen, M. H.; Yin, Q.; You, S.-L.

Title: Knowledge Updates 2014/2

Print ISBN: 9783131762412; Online ISBN: 9783131975010; Book DOI: 10.1055/b-003-125812

1st edition © 2014 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

This update summarizes reactions wherein an alkyl radical is formed by cleavage of an appropriately functionalized C—C bond, followed by trapping of this intermediate by a bromine atom source to afford a bromoalkane. It covers the literature up until late 2013.

Key words

bromination - radicals - carboxylic acids - silver carboxylates - decarboxylation - Hunsdiecker reaction - Cristol–Firth reaction - Barton reaction - 1-(acyloxy)pyridine-2-(1H)-thiones - Barton esters - peroxyacetals
 
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