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Banert, K. et al.: 2014 Science of Synthesis, 2014/3: Knowledge Updates 2014/3 DOI: 10.1055/sos-SD-139-00260
Knowledge Updates 2014/3

39.26.6.2 Cyclic Alkaneselenolates of Group 3–12 Metals (Update 2014)

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Editors: Banert, K.; Brøndsted Nielsen, M.; Drabowicz, J.; Joule, J. A.; Schaumann, E.; Weinreb, S. M.

Authors: Aitken, R. A.; Ameduri, B.; Braverman, S.; Brøndsted Nielsen, M.; Cherkinsky, M.; Heydt, H.; Meehan, A.; Petersen, A. U.; Polo, A.; Real, J.; Stanforth, S. P.; Udmark, J.

Title: Knowledge Updates 2014/3

Print ISBN: 9783131762818; Online ISBN: 9783131975119; Book DOI: 10.1055/b-003-125830

1st edition © 2014 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

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This chapter is an update to the earlier Science of Synthesis contribution (Section 39.26.6) describing methods for the synthesis of cyclic alkaneselenolates of transition metals and their applications in organic synthesis. Synthetic methods developed in recent years concern diselenolates, aminoselenolates, and selenolates with a metal-carbon bond. New applications for this class of compounds in organic synthesis have not been proposed.

Key words

transition metals - bridged compounds - cyclic compounds - selenium compounds - selenides - selenols - oxidative addition - cycloaddition