42.18.2 Pentacoordinated Phosphoranes (Update 2022)

Abstract

This is an update to the previous Science of Synthesis chapter on pentacoordinated phosphoranes (Section 42.18), and covers methods for their synthesis and application published up to 2020. Due to the fact that the past years have seen a considerable number of papers including spirocyclic phosphoranes, reports on the synthesis have been limited to selected spirophosphoranes such as spirohydrophosphoranes, caged phosphoranes, or metallophosphoranes. In addition, some classical examples of the preparation of these types of compound are also discussed in this review.

Key words

phosphoranes - condensation - tautomerization - bicyclic compounds - chiral compounds - Martin ligand - cascade reactions - cage phosphoranes - phosphoranides - substitution - metathesis - metallophosphoranes - apicophilicity - Atherton–Todd reaction - isomerization

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