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Donohoe, T. J. et al.: 2022 Science of Synthesis, 2022/1: Knowledge Updates 2022/1 DOI: 10.1055/sos-SD-142-00235
Knowledge Updates 2022/1

42.18.2 Pentacoordinated Phosphoranes (Update 2022)

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Editors: Donohoe, T. J.; Krause, N.; Marsden, S. P.; Montchamp, J.-L.; Terent'ev, A. O. ; Weinreb, S. M.

Authors: Ayad, T. ; Barsegyan, Y. ; de Lucca, Jr., E. C. ; Haake, E. ; Hutskalova, V. ; Jux, N. ; Montforts, F.-P. ; Munaretto, L. S. ; Pajkert, R. ; Pirat, J.-L. ; Röschenthaler, G.-V. ; Santana, V. C. S. ; Terent'ev, A. O. ; Tius, M. A. ; Tomkinson, N. C. O. ; Sparr, C. ; Vil’, V. A. ; Virieux, D. 

Title: Knowledge Updates 2022/1

Print ISBN: 9783132451476; Online ISBN: 9783132451490; Book DOI: 10.1055/b000000641

1st edition © 2022. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 


Abstract

This is an update to the previous Science of Synthesis chapter on pentacoordinated phosphoranes (Section 42.18), and covers methods for their synthesis and application published up to 2020. Due to the fact that the past years have seen a considerable number of papers including spirocyclic phosphoranes, reports on the synthesis have been limited to selected spirophosphoranes such as spirohydrophosphoranes, caged phosphoranes, or metallophosphoranes. In addition, some classical examples of the preparation of these types of compound are also discussed in this review.

Key words

phosphoranes - condensation - tautomerization - bicyclic compounds - chiral compounds - Martin ligand - cascade reactions - cage phosphoranes - phosphoranides - substitution - metathesis - metallophosphoranes - apicophilicity - Atherton–Todd reaction - isomerization
 
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