47.1. 2.3.3 Asymmetric π-Allyl Substitution Reactions
Buch
Herausgeber: Liu, G.
Titel: Knowledge Updates 2023/1
Print ISBN: 9783132455061; Online ISBN: 9783132455085; Buch-DOI: 10.1055/b000000844
1st edition © 2023 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie
Science of Synthesis Knowledge Updates
Übergeordnete Publikation
Titel: Science of Synthesis
DOI: 10.1055/b-00000101
Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Typ: Mehrbändiges Werk
Abstract
Asymmetric allylic substitution reactions catalyzed by transition-metal complexes, namely, the Tsuji–Trost-type reaction, can be used for constructing stereochemically defined carbon–carbon and carbon–heteroatom bonds. In this review, asymmetric allylic substitution reactions catalyzed by different transition-metal complexes, including those based on palladium, iridium, rhodium, and earth-abundant metals, are discussed. These reactions are categorized by the type of nucleophiles or transition-metal catalysts employed.
Schlüsselwörter
alkenes - allylic substitution - asymmetric catalysis - dual catalysis - earth-abundant metals - enantioselectivity - iridium - palladium - rhodium - stereoselectivity - transition metals- 1 Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis. Kazmaier U. Springer; Heidelberg 2012
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