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Campagne, J.-M.  et al.: 2024 Science of Synthesis, 2023/2: Knowledge Updates 2023/2 DOI: 10.1055/sos-SD-147-00289
Knowledge Updates 2023/2

47.1.9 Alkene Hydrovinylation, Hydroalkenylation, and Cycloisomerization

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Herausgeber: Campagne, J.-M. ; Fernández, E.; Jiang, X. ; Liu, Guosheng ; Wang, M. 

Autoren: Bao, Z.; Ho, C.-Y. ; Hong, C. ; Ouellet-Du Berger, M.-R. ; Paquin, J.-F. ; Raja, D. ; Tovar, D. ; Wang, J. ; Xiao, X.; Yamashita, M. 

Titel: Knowledge Updates 2023/2

Print ISBN: 9783132455191; Online ISBN: 9783132455214; Buch-DOI: 10.1055/b000000845

1st edition © 2024 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Chemische Labormethoden, Stöchiometrie;Organometallchemie

Science of Synthesis Knowledge Updates



Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

This review on homogeneous C-C bond-forming reactions to form alkenes focuses on hydrovinylation, hydroalkenylation, and cycloisomerization, and covers the literature published from ca. 1990 to early 2020. The account is arranged by reaction type, and then further categorized according to the alkene donors and alkene acceptors employed. This chapter highlights the potential of using well-controlled insertion catalysts in the green and catalytic synthesis of higher substituted alkenes. The methods described avoid the stoichiometric use of alkenyl halides and metallic reagents and serve as essential alternatives to those based on Heck reactions and related approaches.

Schlüsselwörter

insertion - alkenes - linear alpha-olefins - dienes - strained alkenes - dimerization - hydrovinylation - hydroalkenylation - cycloisomerization - cyclization - rearrangement - isomerization - oligomerization - transition-metal catalysis - enantioselective catalysis - regioselective catalysis - diastereoselective catalysis - phosphorus ligands
 
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