3.4 Baeyer–Villiger Oxidation

G. de Gonzalo Calvo; W. J.H. van Berkel; M. W. Fraaije

doi:10.1055/sos-SD-216-00079

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Faber, K. et al.: 2015 Science of Synthesis: Biocatalysis in Organic Synthesis 3 DOI: 10.1055/sos-SD-216-00079

Biocatalysis in Organic Synthesis 3

3.4 Baeyer–Villiger Oxidation

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Editors: Faber, K.; Fessner, W.-D.; Turner, N. J.

Authors: Allen, C. C. R.; de Gonzalo, G.; Ellinger, J. J.; Ewing, T. A.; Faber, K.; Fernández-Lucas, J.; Flynn, C. M.; Fraaije, M. W.; García-Junceda, E.; Garrabou, X.; Gkotsi, D. S.; Glueck, S. M.; Goss, R. J. M.; Grogan, G.; Gröger, H.; Grüschow, S.; Hammer, S. C.; Hauer, B.; Herter, S.; Hilvert, D.; Hollmann, F.; Hormigo, D.; Hummel, W.; Molla, G.; Nestl, B. M.; Nolte, J. C.; Obexer, R.; Oroz-Guinea, I.; Patel, R. N.; Pollegioni, L.; Quin, M. B.; Schmidt-Dannert, C.; Smith, D. R. M.; Turner, N. J.; Urlacher, V. B.; van Berkel, W. J. H.; Woodley, J. M.

Title: Biocatalysis in Organic Synthesis 3

Print ISBN: 9783131746610; Online ISBN: 9783131974914; Book DOI: 10.1055/b-003-125814

1st edition © 2015. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry

Science of Synthesis Reference Libraries

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Title: Science of Synthesis

DOI: 10.1055/b-00000101

Type: Multivolume Edition

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Abstract

This chapter describes methods for performing biocatalytic Baeyer–Villiger oxidations in which the final compounds are obtained under mild reaction conditions. In particular, reactions that can be performed with typical Baeyer–Villiger monooxygenases are presented that illustrate the high degree of regio- and/or enantioselectivity and good yields obtained with such enzymes for the synthesis of various compounds with high added value.

Key words

Baeyer–Villiger oxidation - lipases - perhydrolysis - monooxygenases - coenzyme regeneration - desymmetrization - lactones - (dynamic) kinetic resolution - regiodivergence - enantioselectivity

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