1.1 C—C Bond Formation by Arene C—H Activation

F. Melkonyan; V. Gevorgyan

doi:10.1055/sos-SD-217-00003

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Yu, J.-Q.: 2016 Science of Synthesis, 3a: Catalytic Transformations via C—H Activation 1 DOI: 10.1055/sos-SD-217-00003

Catalytic Transformations via C—H Activation 1

1.1 C—C Bond Formation by Arene C—H Activation

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Editor: Yu, J.-Q.

Authors: Carreira, E. M.; Decicco, C. P.; Fuerstner, A.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Title: Catalytic Transformations via C—H Activation 1

Subtitle: C-C, C-N, C-O, C-Hal, and C-B Bond Formation

Print ISBN: 9783131711311; Online ISBN: 9783132403413; Book DOI: 10.1055/b-003-129295

1st edition © 2016 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Title: Science of Synthesis

DOI: 10.1055/b-00000101

Type: Multivolume Edition

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Abstract

The palladium(0)-catalyzed C—H arylation reaction is one of the pioneering transformations in C—H activation chemistry in general. In the past two decades, the method has been extensively developed and now represents a very powerful tool for the construction of C(sp²)—C(sp²) bonds. In this chapter, the palladium(0)-catalyzed C—H arylation of aromatic compounds is reviewed. The application of the method toward the synthesis of polycyclic aromatic hydrocarbons (PAHs), a variety of biaryl compounds, and natural products, with emphasis on the most practical and efficient protocols, are discussed.

Key words

C—H activation - palladium catalysts - arylation - arenes - polycyclic compounds - biaryls - natural products

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