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Yu, J.-Q.: 2015 Science of Synthesis, 3b: Catalytic Transformations via C-H Activation 2 DOI: 10.1055/sos-SD-218-00014
Catalytic Transformations via C—H Activation 2

2.2 C—C Bond Formation by Alkyl C—H Activation

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Book

Editor: Yu, J.-Q.

Authors: Carreira, E. M.; Decicco, C. P.; Fuerstner, A.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Title: Catalytic Transformations via C-H Activation 2

Print ISBN: 9783132057210; Online ISBN: 9783132404137; Book DOI: 10.1055/b-004-129675

1st edition © 2015 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Type: Multivolume Edition

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Abstract

In comparison to the wealth of methods recently developed for the catalytic functionalization of the C(sp2)—H bonds of arenes and hetarenes, relatively little work has focused on the functionalization of the unactivated C(sp3)—H bonds of alkyl fragments. This chapter highlights selected examples of the fast-growing literature on the catalytic functionalization of unactivated C(sp3)—H bonds through organometallic C—H activation, with an emphasis on the most synthetically useful methods. It covers heteroatom-directed C(sp3)—H activation with regard to cross coupling with alkenes, alkynes, and carbon monoxide, organoboron reagents, diaryliodonium salts, and organic halides. Also included is C(sp3)—H activation/intramolecular C—C coupling induced by oxidative addition and nondirected intermolecular C(sp3)—H arylation.

Key words

C(sp3)—H bond activation - carbon—carbon coupling - transition metals - palladium catalysis - ruthenium catalysis - alkylation
 
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