2.5 C—C Bond Formation by Double C—H Activation

J.-B. Xia; S. You

doi:10.1055/sos-SD-218-00066

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Yu, J.-Q.: 2015 Science of Synthesis, 3b: Catalytic Transformations via C-H Activation 2 DOI: 10.1055/sos-SD-218-00066

Catalytic Transformations via C—H Activation 2

2.5 C—C Bond Formation by Double C—H Activation

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Editor: Yu, J.-Q.

Authors: Carreira, E. M.; Decicco, C. P.; Fuerstner, A.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Title: Catalytic Transformations via C-H Activation 2

Print ISBN: 9783132057210; Online ISBN: 9783132404137; Book DOI: 10.1055/b-004-129675

1st edition © 2015 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry

Science of Synthesis Reference Libraries

Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Type: Multivolume Edition

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Abstract

This chapter focuses on transition-metal-catalyzed aryl—aryl bond-forming reactions via double C—H activation. Biaryl scaffolds have received much attention as a privileged structure broadly found in biologically active natural products, pharmaceuticals, agrochemicals, and functional molecules in material sciences, etc. Transition-metal-catalyzed cross-coupling reactions are the most general and efficient methods to synthesize biaryls, but both coupling partners need to be preactivated in transition-metal-catalyzed cross-coupling reactions when compared with simple arenes. Over the past decade, significant advances have been made in transition-metal-catalyzed biaryl synthesis using simple arenes as substrates via C—H activation. This chapter summarizes representative examples of transition-metal-catalyzed biaryl synthesis using two simple arenes as substrates via double C—H activation.

Key words

transition-metal catalysis - double C—H activation - biaryl synthesis - directing groups

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