2.12 C—B Bond Formation by Arene C—H Activation

A. Ros; R. Fernandez; J. M. Lassaletta

doi:10.1055/sos-SD-218-00219

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Yu, J.-Q.: 2015 Science of Synthesis, 3b: Catalytic Transformations via C-H Activation 2 DOI: 10.1055/sos-SD-218-00219

Catalytic Transformations via C—H Activation 2

2.12 C—B Bond Formation by Arene C—H Activation

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Editor: Yu, J.-Q.

Authors: Carreira, E. M.; Decicco, C. P.; Fuerstner, A.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Title: Catalytic Transformations via C-H Activation 2

Print ISBN: 9783132057210; Online ISBN: 9783132404137; Book DOI: 10.1055/b-004-129675

1st edition © 2015 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry

Science of Synthesis Reference Libraries

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Title: Science of Synthesis

DOI: 10.1055/b-00000101

Type: Multivolume Edition

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Abstract

This chapter provides a survey of the most useful available methodologies for the direct borylation of arenes and hetarenes, which proceed in all cases via a C—H activation event mediated by transition metals such as rhodium, iridium, or palladium. The borylation reactions have been organized into two main groups: (1) direct borylations with regioselectivity mainly controlled by steric factors, and (2) site-selective borylation, with regioselectivity driven by directing effects.

Key words

C—H activation - organoboron compounds - borylation - arenes - hetarenes - synthetic methods - rhodium - iridium - palladium - directing groups

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