1.7 Cycloisomerizations of Substrates with Multiple Unsaturated Bonds

Abstract

Transition-metal complexes catalyze cycloisomerizations of substrates bearing multiple unsaturated carbon–carbon bonds. Carbo- and heterocycles are obtained via selective carbon–carbon bond formations with concomitant hydrogen-atom transfer under mild conditions.

Key words

transition-metal catalysts - cycloisomerization - alkynes - alkenes - allenes - 1,3-dienes - carbocycles - heterocycles - regioselectivity - enantioselectivity

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