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Gao, S. et al.: 2016 Science of Synthesis, 2016/4b: Metal-Catalyzed Cyclization Reactions 2 DOI: 10.1055/sos-SD-222-00001
Metal-Catalyzed Cyclization Reactions 2

2.1 Epoxidation and Aziridination Reactions

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Book

Editors: Gao, S.; Ma, S.

Authors: Bora, U.; Dominguez, G.; Du, H.; Garve, L.; Harmata, M.; Hu, W.; Jones, D. E.; Lee, D.; Li, X.; Mondal, M.; Pérez Castells, J.; Sabbasani, V. R.; Shibata, Y.; Tanaka, K.; Tang, W.; Werz, D. B.; Xia, F.; Xu, X.; Ye, S.

Title: Metal-Catalyzed Cyclization Reactions 2

Print ISBN: 9783131998118; Online ISBN: 9783132404823; Book DOI: 10.1055/b-004-129734

1st edition © 2016 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

Due to the strain associated with three-membered rings, epoxides and aziridines react with various nucleophiles to give 1,2-difunctionalized products. This makes them valuable intermediates in organic synthesis, including in the synthesis of bioactive natural and nonnatural compounds. This chapter summarizes recent advances in metal-catalyzed epoxidation and aziridination reactions of alkenes, as well as their synthetic applications.

Key words

epoxidation - aziridination - expoxides - aziridines - alkenes - metal catalysis - cyclization - enantioselectivity - diastereoselectivity - asymmetric synthesis
 
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