2.5 Metal-Catalyzed Asymmetric Diels–Alder and Hetero-Diels–Alder Reactions

H. Du

doi:10.1055/sos-SD-222-00111

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Gao, S. et al.: 2016 Science of Synthesis, 2016/4b: Metal-Catalyzed Cyclization Reactions 2 DOI: 10.1055/sos-SD-222-00111

Metal-Catalyzed Cyclization Reactions 2

2.5 Metal-Catalyzed Asymmetric Diels–Alder and Hetero-Diels–Alder Reactions

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Editors: Gao, S.; Ma, S.

Authors: Bora, U.; Dominguez, G.; Du, H.; Garve, L.; Harmata, M.; Hu, W.; Jones, D. E.; Lee, D.; Li, X.; Mondal, M.; Pérez Castells, J.; Sabbasani, V. R.; Shibata, Y.; Tanaka, K.; Tang, W.; Werz, D. B.; Xia, F.; Xu, X.; Ye, S.

Title: Metal-Catalyzed Cyclization Reactions 2

Print ISBN: 9783131998118; Online ISBN: 9783132404823; Book DOI: 10.1055/b-004-129734

1st edition © 2016 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

This chapter focuses on asymmetric Diels–Alder, oxa-Diels–Alder, and aza-Diels–Alder reactions promoted by various chiral, Lewis acidic metal catalysts. As well as describing the different approaches and catalysts, selected examples of these reactions in the synthesis of natural products and drug molecules are presented.

Key words

asymmetric synthesis - aza-Diels–Alder reactions - Diels–Alder reactions - Lewis acid catalysis - metal-catalyzed reactions - oxa-Diels–Alder reactions

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