2.9 Intramolecular Free-Radical Cyclization Reactions

M. Mondal; U. Bora

doi:10.1055/sos-SD-222-00230

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Gao, S. et al.: 2016 Science of Synthesis, 2016/4b: Metal-Catalyzed Cyclization Reactions 2 DOI: 10.1055/sos-SD-222-00230

Metal-Catalyzed Cyclization Reactions 2

2.9 Intramolecular Free-Radical Cyclization Reactions

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Buch

Herausgeber: Gao, S.; Ma, S.

Autoren: Bora, U.; Dominguez, G.; Du, H.; Garve, L.; Harmata, M.; Hu, W.; Jones, D. E.; Lee, D.; Li, X.; Mondal, M.; Pérez Castells, J.; Sabbasani, V. R.; Shibata, Y.; Tanaka, K.; Tang, W.; Werz, D. B.; Xia, F.; Xu, X.; Ye, S.

Titel: Metal-Catalyzed Cyclization Reactions 2

Print ISBN: 9783131998118; Online ISBN: 9783132404823; Buch-DOI: 10.1055/b-004-129734

1st edition © 2016 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

Science of Synthesis Reference Libraries

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Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Typ: Mehrbändiges Werk

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Abstract

Over the past five decades, the metal-mediated intramolecular free-radical cyclization strategy has developed into a widely applicable synthetic methodology. With properties including wide functional-group tolerance, selectivity, and spatial retention, radical chemistry has attracted considerable attention from chemists dealing with the synthesis and functionalization of diverse organic compounds. The coverage of this chapter is limited to the best methods available for the metal-mediated synthesis of cyclic organic and biomolecular species for practical use in both an academic setting and in industry.

Schlüsselwörter

intramolecular - free-radical - cyclization - manganese(III) acetate - titanocenes - samarium(II) iodide - copper - tandem - cascade - pyrroles - alkylidenes - indoles - azaindolines - indolinones - oxindoles - lactams - quinolines - furans - lactones - phthalides - pyrans - benzopyrans - piperidines - cycloalkanes - cycloalkanols - allyl alcohols - amino alcohols - cyclic ketones - amino ketones - phenanthridines - benzothiazoles - thiophenes - total synthesis

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