1.4. 1 Hydrogenation
Book
Editors: Cazin, C. ; Nolan, S.
Title: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 1
Print ISBN: 9783132012813; Online ISBN: 9783132407633; Book DOI: 10.1055/b-004-132254
1st edition © 2017. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
From the viewpoint of atom economy and cost efficiency, hydrogenation is an ideal way to reduce various multiple bonds. In this chapter, some methods are described for the hydrogenation of alkenes, alkynes, carbonyls and related compounds, and (het)arenes using homogeneous metal–N-heterocyclic carbene (NHC) catalysts. Moreover, this section also covers enantioselective hydrogenations in which chiral NHCs are employed as ligands.
Key words
hydrogenation - partial hydrogenation - asymmetric hydrogenation - transition-metal catalysts - carbene ligands - alkenes - alkynes - ketones - arenes - hetarenes - heterocycles - N-heterocyclic carbenes- 14 Dharmasena, UL, Foucault, HM, dos Santos, EN, Fogg, DE, Nolan, SP. Organometallics. 2005; 24: 1056
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- 33 Angulo, IM, Bouwman, E, van Gorkum, R, Lok, SM, Lutz, M, Spek, AL. J. Mol. Catal. A: Chem.. 2003; 202: 97