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Cazin, C. S. J. et al.: 2017 Science of Synthesis, 2016/5a: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 1 DOI: 10.1055/sos-SD-223-00220
N-Heterocyclic Carbenes in Catalytic Organic Synthesis 1

1.4.7 Hydration

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Editors: Cazin, C. S. J.; Nolan, S. P.

Authors: Albrecht, M.; Baudrenghien, L.; Bielawski, C. W.; Biffis, A.; Cavallo, L.; Cazin, C. S. J.; César, V.; Chetcuti, M. J.; Cuenca, A. B.; de Frémont, P.; Elie, M.; Fairlamb, I. J. S.; Falivene, L.; Fernández, E.; Gagné, M. R.; Gaillard, S.; Huynh, H. E.; Kalck, P.; Kuwano, R.; Lastovickova, D. N.; Lavigne, G.; Makida, Y.; Markó, I. E.; Martin, A. R.; Nahra, F.; Nakao, Y.; Ogasawara, M.; Payne, P. R.; Renaud, J.-L.; Ronson, T. O.; Ruamps, M.; Segarra, C.; Teator, A. J.; Trzeciak, A. M.; Tubaro, C.; Urrutigoity, M.; Vummaleti, S. V. C.; Whittlesey, M. K.; Yuan, D.

Title: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 1

Print ISBN: 9783132012813; Online ISBN: 9783132407633; Book DOI: 10.1055/b-004-132254

1st edition © 2017. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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A. Biffis; C. Tubaro

Abstract

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The application of metal–N-heterocyclic carbene (NHC) complexes as catalysts for the addition of water to multiple bonds in organic substrates is reviewed. Protocols for general and efficient reactions of this kind under mild conditions have been developed, in particular with gold–NHC complexes as catalysts for the hydration of alkynes, which have raised the appeal of this methodology among synthetic organic chemists.

Key words

hydration - alkynes - nitriles - allenes - catalysts - N-heterocyclic carbenes - gold
 
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