1.4. 7 Hydration
Buch
Herausgeber: Cazin, C. S. J.; Nolan, S. P.
Titel: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 1
Print ISBN: 9783132012813; Online ISBN: 9783132407633; Buch-DOI: 10.1055/b-004-132254
1st edition © 2017. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie
Science of Synthesis Reference Libraries
Übergeordnete Publikation
Titel: Science of Synthesis
DOI: 10.1055/b-00000101
Reihenherausgeber: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Typ: Mehrbändiges Werk
Abstract

The application of metal–N-heterocyclic carbene (NHC) complexes as catalysts for the addition of water to multiple bonds in organic substrates is reviewed. Protocols for general and efficient reactions of this kind under mild conditions have been developed, in particular with gold–NHC complexes as catalysts for the hydration of alkynes, which have raised the appeal of this methodology among synthetic organic chemists.
Schlüsselwörter
hydration - alkynes - nitriles - allenes - catalysts - N-heterocyclic carbenes - gold- 11 Ramón RS, Gaillard S, Slawin AMZ, Porta A, DʼAlfonso A, Zanoni G, Nolan SP. Organometallics 2010; 29: 3665
- 15 Brill M, Collado A, Cordes DB, Slawin AMZ, Vogt M, Grützmacher H, Nolan SP. Organometallics 2015; 34: 263
- 23 Fang W, Presset M, Guérinot A, Bour C, Bezzenine-Lafollée S, Gandon V. Chem.–Eur. J. 2014; 20: 5439