2.1. 5 Alkene Metathesis Based Polymerization
Book
Editors: Cazin, C. ; Nolan, S.
Title: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 2
Print ISBN: 9783132414006; Online ISBN: 9783132414044; Book DOI: 10.1055/b-004-140260
1st edition © 2018 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
Alkene metathesis based polymerizations that rely on metal complexes with N-heterocyclic carbene (NHC) ligands are discussed in this chapter. Particular emphasis is placed on novel polymer microstructures, architectures, and applications that have been enabled by NHC–metal complexes. Applications of ruthenium–NHC initiated ring opening metathesis polymerization (ROMP) for the synthesis of block copolymers, branched polymers, stereocontrolled polymers, and cyclic polymers are described. Ruthenium–NHC catalyzed acyclic diene metathesis polymerization (ADMET) and cyclopolymerization are also discussed, along with alkene metathesis polymerizations using tungsten– and molybdenum–NHC complexes.
Key words
N-heterocyclic carbenes - alkene metathesis - polymer chemistry - ring opening metathesis polymerization - acyclic diene metathesis polymerization - cyclopolymerization - living polymerization - metal initiators - bottlebrush polymers - tacticity - star polymers - surface grafting - aqueous polymerization - stereocontrolled polymers - sequence-controlled polymers - alternating copolymers-
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