2.5 Transition-Metal-Catalyzed Oxidations
Buch
Herausgeber: Cazin, C. ; Nolan, S.
Titel: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 2
Print ISBN: 9783132414006; Online ISBN: 9783132414044; Buch-DOI: 10.1055/b-004-140260
1st edition © 2018 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart
Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie
Science of Synthesis Reference Libraries
Übergeordnete Publikation
Titel: Science of Synthesis
DOI: 10.1055/b-00000101
Reihenherausgeber: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Typ: Mehrbändiges Werk
Abstract
The use of transition-metal complexes with N-heterocyclic carbene (NHC) ligands for oxidative catalysis is summarized in this chapter. Special attention is given to the applicability in organic synthesis and the comparison of results for different reaction conditions and catalyst types. The stoichiometric reactivity of NHC–transition-metal complexes (Ru, Co, Ir, Ni, Pd) with molecular oxygen and the stabilization of high-valent metal complexes with chelating ligands are discussed. The oxidation of alcohols to aldehydes and ketones, Wacker-type oxidation, aziridination and epoxidation of olefins, oxidative scission of alkenes to aldehydes, and oxidation of saturated and aromatic hydrocarbons are addressed.
Schlüsselwörter
oxidation - N-heterocyclic carbenes - ligands - catalysis - oxygen - metal - transition-metal complexes - alcohols - alkenes - hydrocarbons - aromatics - aziridination - epoxidation - alkene scission-
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