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Muñiz, K.: 2018 Science of Synthesis, 2017/4: Catalytic Oxidation in Organic Synthesis DOI: 10.1055/sos-SD-225-00172
Catalytic Oxidation in Organic Synthesis

5.3 Aminohydroxylation and Aminooxygenation of Alkenes

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Editor: Muñiz, K.

Authors: Andries-Ulmer, A.; Bellina, F.; Berkessel, A.; Borrell, M.; Caballero, A.; Calleja, P.; Chemler, S. R.; Chen, P.; Costas, M.; Díaz-Requejo, M. M.; Dorel, R.; Dornan, L. M.; Ebner, D. C.; Echavarren, A. M.; Engler, H.; Esguerra, K. V. N.; Farràs, P.; Funes-Ardoiz, I.; Garrido-Barros, P.; Gimbert-Suriñach, C.; Gómez-Arrayas, R.; Griesbeck, A. G.; Gulder, T.; Hughes, N. L.; Ikariya, T.; Ishihara, K.; Jiao, N.; Kayaki, Y.; Kleczka, M.; Leuther, T. M.; Li, Z.; Liu, G.; Llobet, A.; Lumb, J.-P.; Martínez, C.; Maseras, F.; Muldoon, M. J.; Muñiz, K.; Park, N.; Patel, H. H.; Perego, L. A.; Pérez, P. J.; Race, N. J.; Rodríguez, N.; Sigman, M. S.; Sillner, S.; Singh, F. V.; Stoltz, B. M.; Uyanik, M.; Vicens, L.; Wdowik, T.; Wirth, T.; Wright, A. C.

Title: Catalytic Oxidation in Organic Synthesis

Print ISBN: 9783132012318; Online ISBN: 9783132403710; Book DOI: 10.1055/b-003-129345

1st edition © 2018. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Koch, G.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

Also available at
 


Abstract

The aminohydroxylation of alkenes provides β-amino alcohols (vicinal amino alcohols). A number of alkene aminohydroxylation protocols (and those of related reactions termed oxyamination and aminooxygenation), predominantly enabled by transition-metal catalysis, are described in this chapter, which focuses on literature published in the period 1996–2015. Cyclic and acyclic compounds containing vicinal amino alcohols and derivatives thereof can be prepared from alkenes with good regio-, diastereo-, and enantioselectivity.

Key words

alkenes - aminooxygenation - aminohydroxylation - oxyamination - β-amino alcohols - catalysis - osmium catalysts - iron catalysts - rhodium catalysts - copper catalysts - palladium catalysts - manganese catalysts
 
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