1.1.1 Homogeneous Reduction of Alkenes

X. Tan; H. Lv; X. Zhang

Abstract

This chapter is focused on recent progress in the asymmetric hydrogenation of substituted alkenes, and the application of this methodology in the construction of a variety of chiral centers. The asymmetric hydrogenation of nonfunctionalized alkenes, α,β-unsaturated carbonyl compounds, enamides, enols, and other heteroatom-substituted alkenes is covered.

Schlüsselwörter

alkenes - alkanes - olefins - transition-metal catalysis - asymmetric hydrogenation - phosphorus ligands - homogeneous catalysis - reduction - rhodium - iridium - ruthenium

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