1.12 Catalytic Hydrodehalogenation Reactions

Abstract

Hydrodehalogenation, or reductive dehalogenation, is an important organic transformation that is often used as a detoxification process in industry. A number of methods have been employed to effect this transformation in organic synthesis. Metal-catalyzed hydrodehalogenation is among the popular methods and is typically performed with molecular hydrogen or via transfer hydrogenation from other reagents. The current review highlights development in metal-catalyzed hydrodehalogenation reactions in the last 15 years, where protocols to afford spectroscopically characterized reaction products have been established.

Key words

dehalogenation - heterogeneous catalysis - homogeneous catalysis - reduction - haloalkanes - alkanes - haloarenes - arenes - transition-metal catalysis - photoredox catalysis

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