7 Very Fast Reactions and Extreme Conditions

H. Kim; J. Yoshida

Abstract

Microreaction technology represents a powerful and unique tool for the control of extremely fast reactions and reactions under extreme conditions. In this chapter, fast flow reactions such as Swern–Moffatt oxidations, diisobutylaluminum hydride reductions, reactions involving organolithiums and organomagnesiums, and Friedel–Crafts alkylations are presented. Moreover, this chapter also covers examples of reactions performed under extreme reaction conditions of high temperature and high pressure, which cannot be easily conducted in flasks.

Schlüsselwörter

fast reactions - unstable intermediates - organolithiums - extreme conditions - high temperature - high pressure - flow chemistry - microreactors - flash chemistry

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