6 Proton-Coupled Electron Transfer

S. M. Thullen; M. A. Ashley; T. Rovis

doi:10.1055/sos-SD-229-00118

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König, B.: 2019 Science of Synthesis, 2018/6: Photocatalysis in Organic Synthesis DOI: 10.1055/sos-SD-229-00118

Photocatalysis in Organic Synthesis

6 Proton-Coupled Electron Transfer

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Buch

Herausgeber: König, B.

Autoren: Akita, M.; Albero, J.; Amador, A. G.; Ashley, M. A.; Brasholz, M.; Corcé, V.; DiRocco, D. A.; Dix, S.; Ehrnsberger, P.; Fensterbank, L.; Gaida, F.; García, H.; Ghosh, I.; Gilmour, R.; Griesbeck, A. G.; Gutiérrez Bonet, Á.; Hepburn, H. B.; Hopkinson, M. N.; Kelly, C. B.; Koike, T.; Laha, R.; Lang, S. B.; Leonori, D.; Lévêque, C.; Li, P.; Lu, L.-Q.; Matsui, J. K.; Melchiorre, P.; Metternich, J. B.; Molander, G. A.; Mudd, R. J.; Ollivier, C.; Pandey, G.; Phelan, J. P.; Reiser, O.; Rey, Y. P.; Rovis, T.; Ruffoni, A.; Scholz, S. O.; Schultz, D. M.; Skubi, K. L.; Speckmeier, E.; Thullen, S. M.; Vollmer, M.; Wang, L.; Wang, M.; Wei, Y.; Xiao, W.-J.; Yoon, T. P.; Zeitler, K.; Zhou, Q.-Q.

Titel: Photocatalysis in Organic Synthesis

Print ISBN: 9783132417021; Online ISBN: 9783132417069; Buch-DOI: 10.1055/b-006-161273

1st edition © 2019. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

Science of Synthesis Reference Libraries

Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

Proton-coupled electron transfer (PCET) enables the functionalization of prevalent organic moieties that are commonly regarded as energetically inaccessible. This chapter focuses on reductive and oxidative PCET in organic systems and the variety of catalyst systems that allow for the formation of ketyl and amidyl radicals for C–C and C–N bond-forming reactions.

Schlüsselwörter

photocatalysis - proton-coupled electron transfer - oxidative PCET - reductive PCET - amidyl radicals - ketyl radicals - homolysis - radical cyclization - [1,5]-hydrogen-atom transfer - asymmetric induction

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