8 Copper-Based Photocatalysts for Visible-Light-Mediated Organic Transformations
Buch
Herausgeber: König, B.
Titel: Photocatalysis in Organic Synthesis
Print ISBN: 9783132417021; Online ISBN: 9783132417069; Buch-DOI: 10.1055/b-006-161273
1st edition © 2019. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie
Science of Synthesis Reference Libraries
Übergeordnete Publikation
Titel: Science of Synthesis
DOI: 10.1055/b-00000101
Reihenherausgeber: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Typ: Mehrbändiges Werk
Abstract


Copper(I) and copper(II) complexes prove to be a powerful alternative to common photocatalysts based on ruthenium, iridium, or organic dyes. A distinct feature is their ability to interact with substrates beyond electron or energy transfer, allowing unique transformations that are otherwise not possible.
Schlüsselwörter
photocatalysis - asymmetric synthesis - aziridines - cycloadditions - cyclobutanes - cyclopropanes - Diels–Alder - endoperoxides - Lewis acids - nitrenes - photochemistry - radical anion - radical cation - triplet state - visible light - [2 + 1] - [2 + 2] - [3 + 2] - [4 + 2] - [2 + 2 + 2]- 15 Minozzi C, Caron A, Grenier-Petel J.-C, Santandrea J, Collins SK. Angew. Chem. Int. Ed. 2018; 57: 5477
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