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König, B.: 2019 Science of Synthesis, 2018/6: Photocatalysis in Organic Synthesis DOI: 10.1055/sos-SD-229-00329
Photocatalysis in Organic Synthesis

19 Heterogeneous Photocatalysis in Organic Synthesis

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Editor: König, B.

Authors: Akita, M.; Albero, J.; Amador, A. G.; Ashley, M. A.; Brasholz, M.; Corcé, V.; DiRocco, D. A.; Dix, S.; Ehrnsberger, P.; Fensterbank, L.; Gaida, F.; García, H.; Ghosh, I.; Gilmour, R.; Griesbeck, A. G.; Gutiérrez Bonet, Á.; Hepburn, H. B.; Hopkinson, M. N.; Kelly, C. B.; Koike, T.; Laha, R.; Lang, S. B.; Leonori, D.; Lévêque, C.; Li, P.; Lu, L.-Q.; Matsui, J. K.; Melchiorre, P.; Metternich, J. B.; Molander, G. A.; Mudd, R. J.; Ollivier, C.; Pandey, G.; Phelan, J. P.; Reiser, O.; Rey, Y. P.; Rovis, T.; Ruffoni, A.; Scholz, S. O.; Schultz, D. M.; Skubi, K. L.; Speckmeier, E.; Thullen, S. M.; Vollmer, M.; Wang, L.; Wang, M.; Wei, Y.; Xiao, W.-J.; Yoon, T. P.; Zeitler, K.; Zhou, Q.-Q.

Title: Photocatalysis in Organic Synthesis

Print ISBN: 9783132417021; Online ISBN: 9783132417069; Book DOI: 10.1055/b-006-161273

1st edition © 2019. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

Also available at
 


Abstract

In recent years, heterogeneous photocatalysis has emerged as a very appealing approach, not only for the degradation of pollutants, but also for the synthesis of chemicals. Although the main use of heterogeneous photocatalysis so far has been the mineralization and complete degradation of organic compounds, interest in the application of heterogeneous (photo)catalysts in organic synthesis is growing due to their potential application in the fabrication of renewable fuels as well as in the preparation of compounds and intermediates especially valuable to the chemical industry, such as pharmaceuticals or polymers. The synthesis of organic molecules assisted by heterogeneous photocatalysts has been dominated by the use of inorganic metal oxide semiconductors, especially titanium(IV) oxide; the use of other semiconductor materials, such as inorganic chalcogenides, carbon-based semiconductors, or metal–organic frameworks has been less explored. In this chapter we show that, in spite of the potential and the large number of heterogeneous photocatalysts already studied, the state of the art of heterogeneous photocatalysis in organic synthesis is still unsatisfactory and much below expectation, particularly in reactions other than oxidation and reduction, such as cross couplings, oxidative decarboxylations, and cycloadditions.

Key words

photocatalysis - heterogeneous catalysis - semiconductors - metal oxides - titanium(IV) oxide - charge separation - metal–organic frameworks (MOF) - graphene - oxidation - reduction - cross coupling - cycloaddition
 
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