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Fernández, E.: 2020 Science of Synthesis, 2019/6: Advances in Organoboron Chemistry towards Organic Synthesis DOI: 10.1055/sos-SD-230-00085
Advances in Organoboron Chemistry towards Organic Synthesis

7 Borylative Ring Opening

Weitere Informationen

Buch

Herausgeber: Fernández, E.

Autoren: Aggarwal, V. K.; Ahmed, E.-A. M. A. ; Aiken, S. G.; Bateman, J. M.; Boldrini, C.; Bose, S. K. ; Carbó, J. J. ; Cho, H. Y.; Clark, T. B. ; Fernández, E.; Fu, Y. ; Geetharani, K. ; Gong, T.-J. ; Ito, H. ; Kitanosono, T.; Kobayashi, S.; Kubota, K. ; Maseras, F. ; Ohmiya, H. ; Pineschi, M.; Ping, Y.; Sawamura, M. ; Wang, J. ; Wang, Y.-F.; Wu, C.; Xu, L. ; Yoshida, H. ; Zhang, F.-L.

Titel: Advances in Organoboron Chemistry towards Organic Synthesis

Print ISBN: 9783132429710; Online ISBN: 9783132429758; Buch-DOI: 10.1055/b-006-164898

2020 © 2020. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

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Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

This review describes published methods for the direct introduction of a boron atom into organic molecules by ring opening of strained cyclic systems using nucleophilic diboron species. Considering the synthetic versatility of functionalized organoboron derivatives, the newly formed carbon–boron bond thus installed paves the way for a wide range of useful subsequent transformations.

Schlüsselwörter

borylation - nucleophilic diboron species - boronic esters - ring-opening reactions - vinyl epoxides - vinyl aziridines - vinylcyclopropanes - propargylic epoxides - propargylic aziridines - propargylic oxetanes - epoxides - aryl aziridines - transition-metal catalysis
 
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