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Molander, G. A.: 2020 Science of Synthesis, 2019/4: Dual Catalysis in Organic Synthesis 1 DOI: 10.1055/sos-SD-231-00003
Dual Catalysis in Organic Synthesis 1

1.1.1 General Principles of Metal/Metal Dual Catalysis

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Book

Editor: Molander, G. A.

Authors: Barriault, L.; Bhoyare, V. W.; Hashmi, A. S. K.; He, R.; Huo, X.; Kim, U B.; Lee, S.-g.; Molander, G. A.; Muralirajan, K.; Nakao, Y.; Patil, N. T.; Primer, D. N.; Riant, O.; Rohe, S.; Rout, S. K.; Rueping, M.; Shi, X.; Tathe, A. G.; Tellis, J. C.; Wang, J.; Zhang, W.; Zidan, M.

Title: Dual Catalysis in Organic Synthesis 1

Print ISBN: 9783132429765; Online ISBN: 9783132429802; Book DOI: 10.1055/b-006-164899

1st edition © 2020. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

The background and principles of dual metal/metal catalysis are briefly introduced in this section, with a particular focus on novel C–C bond-forming cross-coupling-type reactions. By taking advantage of synergistic dual metal/metal catalysis, these transformations have provided the synthetic and organometallic communities with new ideas to design challenging transformations that are difficult to catalyze using a conventional, single metal catalyst.

Key words

dual catalysis - transition-metal catalysis - synergistic catalysis - cross coupling - Sonogashira reaction - Stille reaction - C–H arylation - allylic alkylation - arylboration