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Fensterbank, L. et al.: 2021 Science of Synthesis, 2020/5: Free Radicals: Fundamentals and Applications in Organic Synthesis 2 DOI: 10.1055/sos-SD-233-00066
Free Radicals: Fundamentals and Applications in Organic Synthesis 2

2.4 Redox-Active Ligands in Catalysis for Single-Electron-Transfer Processes

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Buch

Herausgeber: Fensterbank, L.; Ollivier, C.

Autoren: Bartulovich, C. O.; Bolduc, T. G.; Chciuk, T. V.; Chemla, F.; Clark, K. F.; Cormier, M.; Das, A. ; Desage-El Murr, M. ; Dimitrova, D.; Fagnoni, M. ; Flowers, R. A. II; Fukuyama, T. ; Goddard, J.-P. ; Hessin, C.; Liu, Z.-Q. ; Lu, Y.; Mitsudo, K.; Murphy, J. A.; Pérez-Luna, A. ; Protti, S. ; Qin, T. ; Ravelli, D. ; Ren, Y.; Ryu, I. ; Sammis, G. M.; Sibi, M. P.; Subramaniann, H.; Suga, S.; Sumino, S. ; Thomson, B.; Yamago, S.; Zhou, M.

Titel: Free Radicals: Fundamentals and Applications in Organic Synthesis 2

Print ISBN: 9783132435544; Online ISBN: 9783132435551; Buch-DOI: 10.1055/b000000086

1st edition © 2021. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Fachgebiete: Organische Chemie;Chemische Reaktionen, Katalyse;Organometallchemie;Chemische Labormethoden, Stöchiometrie

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Übergeordnete Publikation

Titel: Science of Synthesis

DOI: 10.1055/b-00000101

Reihenherausgeber: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Typ: Mehrbändiges Werk

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Abstract

Redox-active ligands are well known for their ability to stabilize electronic density on their scaffolds, and coordination complexes with such ligands are often stable, open-shell species. This property can be used as a means to favor single-electron transfer (SET) with external sources and devise catalytic radical manifolds. This chapter highlights selected representative reactions resulting in efficient and broad-scope catalytic methodologies. It covers nitrene and carbene radical reactivity, as well as radical trifluoromethylation.

Schlüsselwörter

redox-active ligands - radicals - single-electron transfer - nitrenes - carbenes - trifluoromethylation - aziridines - cyclopropanes - C—H functionalization - porphyrins - transition-metal complexes
 
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