2.9 Electrochemical Organic Synthesis via Radical Species
Book
Editors: Fensterbank, L.; Ollivier, C.
Title: Free Radicals: Fundamentals and Applications in Organic Synthesis 2
Print ISBN: 9783132435544; Online ISBN: 9783132435551; Book DOI: 10.1055/b000000086
1st edition © 2021. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Fürstner (Editor-in-Chief), A.; Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.
Type: Multivolume Edition
Abstract
An electrochemical single-electron-transfer reaction is a promising method to generate reactive radical species in organic synthesis. One-electron oxidation of a neutral compound gives a radical cation, which usually breaks down into a radical and a cationic species; conversely, one-electron reduction of a neutral compound affords a radical anion, which forms a radical and an anionic species. The radical species generated in this way can be used for a variety of transformations. In this chapter, selected recent electrochemical transformations that involve electrogenerated radical species are collected and described.
Key words
electrochemistry - electroorganic chemistry - radical species - single-electron-transfer reaction - one-electron oxidation - one-electron reduction - electrochemical oxidation - electrochemical reduction - nitrogen-centered radicals - sulfur-centered radicals - carbon-centered radicals-
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