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Ackermann, L. : 2022 Science of Synthesis, 2021/5: Electrochemistry in Organic Synthesis DOI: 10.1055/sos-SD-236-00331
Electrochemistry in Organic Synthesis

15 Paired Electrolysis

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Editor: Ackermann, L. 

Authors: Ackermann, L. ; Brown, R. C. D. ; Enders, P.; Fang, P.; Folgueiras-Amador, A. A. ; Francke, R. ; Galczynski, J.; Gosmini, C. ; Hodgson, J. W.; Hou, Z.-W.; Huang, H.; Huang, Z.; Inagi, S. ; Kuciński, K. ; Kuriyama, M. ; Lam, K. ; Lambert, T. H.; Leech, M. C. ; Lennox, A. J. J. ; Lin, Z.; Little, R. D.; Massignan, L.; Mei, T.-S.; Meyer, T. H.; Moeller, K. D. ; Onomura, O. ; Prudlik, A.; Ruan, Z. ; Scheremetjew, A. ; Schiltz, P.; Selt, M.; Villani, E. ; Waldvogel, S. R. ; Wang, Z.-H.; Wu, T.; Xing, Y.-K.; Xu, H.-C. ; Yamamoto, K. 

Title: Electrochemistry in Organic Synthesis

Print ISBN: 9783132442122; Online ISBN: 9783132442146; Book DOI: 10.1055/b000000126

1st edition © 2022. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

While paired electrochemical reactions have a history that can be traced back to the 19th century and have been very effectively used for the production of commercial products, the larger synthetic community has only recently started to embrace the opportunities this approach offers to maximize the overall energy and atom efficiency of electrochemical processes. In this review, a summary of these efforts is presented in the context of four classes of paired electrochemical reactions. These classes of reaction involve parallel processing of products at the anode and cathode, divergent reactions that use a single starting material in different ways, convergent reactions that combine products made at the anode and cathode, and sequential reactions that pass a substrate between the electrodes.

Key words

electroorganic chemistry - paired electrochemistry - anodic oxidation - cathodic reduction
 
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