1.13 Nickel-Catalyzed Cross Coupling Involving Alkenes

Abstract

Nickel-catalyzed functionalization of alkenes to give value-added products in a manner that is rapid, selective, and modular has resulted in tremendous advances in synthetic chemistry. Great progress has been achieved in nickel-catalyzed (migratory) hydrofunctionalization and difunctionalization of alkenes over the past few years. In the first half of this chapter, nickel-catalyzed (migratory) hydrofunctionalization of alkenes is described. The second half details nickel-catalyzed difunctionalization of alkenes. Both reductive and redox-neutral reactions are discussed.

Key words

alkenes - asymmetric catalysis - chain-walking - cross-coupling reactions - difunctionalization - hydrofunctionalization - isomerization - metal hydrides - nickel catalysis - regioselectivity - transition-metal catalysis

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